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If you keep talking to Bill's grandfather on route 25 and show him the Pokemon he asks for, eventually he will ask to see a "Pokemon with 6 tails", meaning Vulpix. Show him a vulpix and he will give you a fire stone. Or, once you get all 16 badges, you can purchase it with your athlete points at the Pokeathlon dome on certain days.

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Q: Where can you get a firestone in Pokemon SoulSilver?
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