to get slugma in your pearl you need to get the nattional dex and then go to stark moountain and go in the inside and you could find wild slugmas
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Slugma evolves into Magcargo.
Slugma can be found in stark mountain, which is the same place you get heatran.
you catch slugma at route 113 and in the fiery path
Slugma evolves into macargo at level 38
at lvl 30