You can find the TM24 - Thunderbolt in Pokemon Pearl or Diamond in two places. One is in the Valley Windworks, after you obtain the Hearthome City gym badge and the HM03 - Surf. Simply Surf behind the Valley Windworks building to a small patch of land. That is where the TM24 is. You can also buy a Thunderbolt TM from the Veilstone Game Corner for 10,000 Coins.
You can find the TM 24 Thunderbolt in diamond and pearl in two convenient places the first 1 is at the valley windworks where you see a patch of sea surf but go north and then east u will find a poke ball there and inside u can obtain the TM 24 thunderbolt and i don't think there r any hidden items and i recommend teachin it to a imported ampharos or a pikachu and riachu o and also u will HAVE TO HAVE THE HM SURF
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you do not find dialga in Pokemon pearl
Get a Pokemon with surf. then go to the bridge in between Floaroma Town and Valley windworks. Surf to the right of the bridge. There will be an electrizer and a thunderbolt TM.
You can find Aron only in Diamond.
Well, you can't find Smoochum in Pokemon Pearl unless you transfer it from a GBA game. Sorry.
TM24 (Thunderbolt) is located in the P2 Laboratory.