Route 208 with sapphire inserted into your ds
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The only way is the Pal Park.
Route 208, Route 210 (After obtaining the National Pokedex, insert Sapphire cartridge into your DS).
In Sapphire and Emerald, you can find Seviper at Route 114. In Diamond, Pearl, and Platinum, Route 208(Sapphire has to be in the GBA slot.).
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