You can get a Vulpix in Mt. Pyre it is (near Lilicove) go to the top and go out. Then you will see grass areas, look for Vulpix. Don't go all the way to the top though, only the area before the fog appears Hint: to get a Ninetales you need a fire stone.
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you have to migrate vulpix from Pokemon emerald,sapphire or ruby
You find a Vulpix on the big tower west of Lilycove… You know, where Archie and T/A are.You can also catch Duskull, another good Pokemon. They are at about Level29-33.
I'm not sure if you can catch Vulpix in Platinum but I do know that you can migrate it from either Pokemon Sapphire or Emerald, and some sources say you can even get Vulpix from Pokemon Leafgreen. I hope this helped.
You can't find a Vulpix in Pokemon FireRed version. That pokemon is version-exclusive to Pokemon LeafGreen.
in MT.pure