Beat the Pokemon League obtain the National Pokedex then enter the safari zone that is north of Route 121; go northeast of the entrance where the construction workers were standing they will be gone. Houndour is found in area 6, but there is a 5% chance of finding it. They are at levels 36-39 Route 121 is East of Lily cove City
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You cannot catch houndour in Pokemon leafgreen either get one from Pokemon emerald or Pokemon colosseum.
Houndour can't be caught in firered so get one from emerald or colosseum.
Since you can't catch houndour your going to have to trade the Pokemon colosseum houndoom to firered breed it then hatch the egg to get houndour or you can get one from emerald's safari zone.
You get a houndour then evolve it i will update when I find out where to catch houndour
Yes, it is in Safari Zone (After you get the National Dex) and in Altering Cave.