go west of sunyshore city, and go in the patch of tall grass all the way to the far left there you can catch a level 100 golden flaffy, you can capture a red staraptor level 100, but you have to run in the grass with a max repel on. you must run 500 times in this pactch of grass. i caught 3 shiny Pokemon doing this.
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The same way you would catch a normal Pokemon. The only difference is is that the Pokemon is shiny.
It takes luck to come across a shiny, but when you find one you catch it like you would catch a regular Pokemon.
No they programmed the game so you can't catch shiny victini, reshiram, and zekrom. All other pokemon can be found shiny.
You can't catch shiny legendary Pokemon without cheats... sorry
you cant