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It depends on what generation of games you are playing, but in the 4th Generation it learns Triple kick at level 19. If you need more info you should check out a site called bulbapedia.bulbagarden.net Here you can find all the moves a Pokemon learns at at what level, in games from Red and Blue to Black and White.
knowledge-seeking eager to learn
No Pokemon can learn more than four moves.
Yes in some ways. They get you to think more. So,..... I guess it would help you learn more. Of course, it would depend on which game you play. Strategy games do not necessarily help you learn more but make you think in different ways that can make you better at solving certain types of problems.
One can learn more on video captions by reading the Technology Today magazine. They have a lot of articles on technology about video captions and how to use them.