you go from solaceon town up to route 210 and slightly northwest from the cafe cabin and youll see 4 psyducks in between trees hope this helps!
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The Psyducks are right above Solaceon City.
You get the potion from Cynthia at Valor Lakefront. Then go to route 210 where the psyducks are.
you go to lake valor, where you'll meet the Pokemon master Cynthia. she'll give you the secretpotion, which you spray on the psyducks to get past them.
After you have defeated leader wake in pastoria city, Cynthia will give you a secretpotion, go to the psyducks and they will go away
You have to get this medicine from some girl. You can find her by going all the way to the right and go down to the next town. Explore for a bit and you'll find her.