You can't.
Pokemon Pearl is a NDS game, and VBA (visual boy advance) can only play Gameboy Advance games.
For Pokemon Pearl, you have to look for NosGBA or another NDS Emulator.
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you do not find dialga in Pokemon pearl
You can find Aron only in Diamond.
Well, you can't find Smoochum in Pokemon Pearl unless you transfer it from a GBA game. Sorry.
your ds emulator should have a option where you can load a gameboy game in the bottom slot(or so to speak) than you have to go to where you can catch transfered pokemon like in diamond and pearl.
Yes.