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No, Togekiss cannot learn Brave Bird.
Pigdeot is not able to learn Brave Bird.
Staraptor learns Brave Bird at Level 49.
Brave Bird is one of Skarmory's egg moves so you can have a female Skarmory as well as male Farfetch'd, Staraptor, Ducklett, Swanna, Swellow, Taillow, Pidgeot, Pidgey, Zubat, Crobat, Pidgeotto, Golbat, Doduo, Dodrio, Honchkrow or Murkrow that knows the Brave Bird attack and then you can place the two into the Daycare and then the Daycare Man will give you an egg that will hatch into a Skarmory that knows Brave Bird.
i believe staraptor can