Pigdeot is not able to learn Brave Bird.
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Staraptor learns Brave Bird at Level 49.
Neither Murkrow or Honchkrow are able to learn Brave Bird.
No, Togekiss cannot learn Brave Bird.
Just level it up until level 49 or at least that is wat level mine learned it
Brave Bird is not a TM in the game. Some Pokemon, mostly Flying-type Pokemon, can learn the move by level up and/or by breeding.