riolu evolves when he is really happy
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You haven't made it far then. You can catch old pokemon. Yes, you can catch Riolu in the challenger's cave after you beat the elite 4. He's rare though.
Riolu is 4 generation Pokemon. You can get egg only in Pokemon Diamond and Pearl
Riolu does not evolve at a specific level, its evolution is related to happiness. While levelling up does increase happiness, in theory a Riolu can evolve at Lv2 if happiness is increased by other methods.
Grovyle evoles into Torterra.
When he/she has good moves. Then evole into vortex