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There is currently no concrete evidence that Brock's Happiny evolves at all. However, the penultimate Diamond and Pearl episode's title has been revealed as "Pokémon Doctor - Brock!" and so rumours have started up is some forums that Happiny evolves in this episode and Brock decides to leave Ash to become a Pokémon doctor.

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Q: When does brock's happiny evolve?
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