Charmander learns metal claw at level 13.
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Charmander learns Metal Claw at level 13. Level up Charmander into Charmeleon, thus giving you at Charmeleon with Metal Claw.
level 13
the moves charmander learns go as: level 7- ember, level 13- metal claw
Raise your charmander to lvl. 13 and it will learn metal claw. Use Metal Claw to defeat Brock since it is super-effective against rock-type Pokemon.
If this is the case, you're playing a game other than FireRed and LeafGreen. Charmander only learns Metal Claw in these games, as a method of defeating Brock's Rock-type Pokemon.