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Give it to the guy who asked you to get the goods back in rustboro city.
You deliver Devon's Goods to Captain Stern who is in Slateport City's museum.
head back to the Devon building to report mission sucsess
You go to slateport and you deliver the Devon goods to captain stern.
To get the PokeNav, you have to deliver the Devon Goods to Devon, the scientist from Devon Corporation. Obtain these by beating the Team Magma Grunt in Rusturf Tunnel. Once you've done that, the president will give you the PokeNav.Note: This is for Ruby. I'm not sure if this applies to Emerald, Sapphire, or anything else.