Super rod use it in viridian city.
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You have to use a good or super rod in route 6 and the other routes I can't remember lol
Yes there are a few locations where you can find Poliwhirl in the wild specifically in the water one spot that has worked the best for me is Viridan City. Use the Super Rod in the small pool left from the Pokemon Center a couple times until it appears.
you can get a poliwhirl or a poliwag and evolve to poliwhirl!! then trade poliwhirl holding a king's rock.
good rod or super rod next to bills house.You can also catch a Poliwhirl there.Poliwag is not in leafgreen you get horsea instead via the good rod and super rod. To get poliwag trade one from firered.
Use a super rod in the water in viridian city.