You should use about 60 or less ultra balls,timer balls.I suggest using the timer
NEVER USE MASTERBALL
balls because they are twice the power of an ultra ball.But that's just my opinion.If you want to be the real deal try the pokeball.I bet your saying that "that's impossible your nuts!" I am not nuts, i have some moves you can do to get groudon(or any powerful Pokemon or legendary Pokemon.)for this, the regular pokeballs will be 45 min. or more. If you are lucky you can get groudon in a regular pokeball in less then 45 min.
press 'a' button every time the Pokemon is in pokeball. and press 'a' a bunch of times when the Pokemon is in the poke balls.
press 'a' and 'b' every time the Pokemon is in the pokeball,if the Pokemon escapes let go of the 'b' button and keep on holding 'a'.Then press select. this will make the Pokemon a higher chance of catching it in the pokeball. hope it works !best likely use an ultra or timer ball.
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Dive ball.
you use a pokeball
Any pokeball will work but an ultra ball is probably best.
an ultra ball
Yes, You can catch Groudon in Pokemon Emerald.