In Pokémon Platinum, the moves that Rotom can learn via level up are Astonish, Trick, Cofuse Ray, Thunder Waave, Uproar, Thundershock, Omnious Wind, Double Team, Shock Wave, Charge, Discharge and its final level-up move which is Substitute.
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You can trade them to the move tutors so that your Pokemon can learn different moves.
Go to serebii.net and TADAA!! you will see what you were searchin for
Rotom is NOT a bad Pokemon his moves by levelling up isTrickAstonishThunderwaveThundershockConfuse RayUproarDouble teamShock waveOminous WindSubstituteChargeDischargehis moves learned by changing forms are:Heat Rotom (oven)OverheatWash Rotom (Washing Machine)Hydro PumpFrost Rotom (Fridge)BlizzardFan Rotom (Rotary Fan)Air SlashMow Rotom (Lawnmower)Leaf Stormgetting different forms of rotom requires a secret key wifi event which is now overgetting it on heartgold and soulsilver- just go into silph co. (saffron city kanto) with rotom first in your party go to the elevator rotoms elctricity will power the elevator and will take you to a room where rotom can posses some appliances.have fun with rotom- he's AWESOME!
go to the old mans house on route 228 he will teach starter Pokemon powerful moves
By using Sunny day, Hail, Rain Dance. Moves that It can learn