TM 1,3,6,7,9,10,11,13,14,15,17,18,19,21,22,27,31,32,42,43,44,45,46,52,53,56,58,60,68,70,75,78,82,83,86,87,90 and HM 3,4,6,7,8
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To my knowledge Ludicolo does not learn Hydropump, however, Lombre learns hydropump at level 49.
By breeding it with a Pokémon that knows Razor Leaf, such as Shiftry or Tropius, then evolving the hatched Lotad into a Ludicolo.
It would be best, in my opinion, to just evolve it into Ludicolo. The physical Pokemon is more important then one move.
Poison types moves are super effective to grass type and neutral to water type