he learns it not by level but he could just level him up to 40 then fight a bunch of unknowns or other Pokemon (only phychic Pokemon) one you level him up by one level while fighting a psychic Pokemon and he will learn psychic
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It evolves at level 25.
Xatu is not a legendary Pokemon
Xatu can be caught in the Safari Zone.
Battle a Pokémon that can use wish(eg Natu or Xatu), and get Smeargle to use sketch when it uses wish.
no it doesnt