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Victini cannot learn V-generate also known as V-create naturally. V-create is a special move that only event Victini can have.
You can get a Victini that's lvl 50 with V-create through an event. Other than that, you can't.
V-create,Fusion Flare,Fusion bolt,Searing shot
You have to level Shroomish to level 45 (Gen V) to learn it then you can evolve, after evolution there is no way for it to learn it.
Level 61 in Generation II and III. Level 64 in Generation IV. Level 67 in Generation V.