Sunkern evolves via the sun stone.
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it evovles at level 18
Sunkern evolves by giving it a Sun Stone, not by leveling up
Darumaka evolves into Darmanitan at level 35.
Purrloin evolves at level 20. -Hope this helps! ;)
You have to use the sun stone on sunkern at any level but it is hard to get a sun stone in soul silver.