Purrloin evolves at level 20.
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it evovles at level 18
Darumaka evolves into Darmanitan at level 35.
Level it up to level 50. It will evolve into Zweileous. Level it up to 64 and you have a Hydreigon.
Aron evolves into Lairon at level 32 and Lairon evolves into Aggron at level 42.
Sunkern evolves via the sun stone.