Yes.Pikachu learns Electro Ball at lv 18
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Pikachu learn electro ball at level 18
No, electro ball can only be found in pokemon black and white so far.
No, Pikachu is not capable of learning Electro Ball in Pokémon Emerald. Pokémon Emerald is a Generation 3 game and Electro Ball was a Pokémon attack that was created and introduced for the Generation 5 games.
Pikachu can only learn volt tackle if you have a ditto in the day care and you catch a pikachu with a light ball in its possesion. Then you have to bring the pikachu to the day care and hatch the egg, then your new pichu will learn volt tackle!!!!!!!!Pikachu Learns ThunderBolt at level 26 (95 Pwr)(15 PP)
There is only one way to get Volt Tackle. You have to breed a female Pikachu or Raichu holding a Light Ball with any Pokémon in the same egg group as Pikachu. If the Pikachu and its partner are put into the daycare, Pichu will have Volt Tackle.