Level 49
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Flygon cannot learn Stone-Edge by level up, only by using TM71 Stone-Edge in the 4th-gen games.
Yes golem is a good Pokemon to have it can learn good moves like stone edge double edge and earthquake and more. but don't teach it like selfdestruct or explosion. it also has highattack and defense
After earthquake (level 33) he learns Explosions at level 38, Double-Edge at level 44, and finally stone edge at level 49 After that he has no more moves that he can learn that are not tms (source The official Pokemon johto guid and johto pokedex, Pokemon Heartgold version soulsilver version Published in japan 2009 by media factory, inc.)
Stone edge is a move that was invented in diamond and pearl and platinum you cannot have any Pokemon learn 4th generation moves like stone edge in firered because they don't exist. But you can migrate a aerodactyl to diamond or pearl or platinum and have it learn stone edge there.
At level 55, Pupitar evolves into Tyranitar. Pupitar is able to learn several moves depending on the level, including stone edge, and rock slide.