It learns thunder wave at level 4
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The moves that Electrike can learn in Pokémon Emerald are Thunderbolt, Thunder, Shock Wave, Thunder Wave, Tackle, Leer, Howl, Quick Attack, Odor Sleuth, Spark, Roar, Bite, Charge, Return, Frustration, Toxic, Roar, Protect, Hidden Power, Rain Dance, Iron Tail, Double Team, Facade, Secret Power, Attract, Rest, Thief, Flash and Strength.
No.
Lv1:Tackle Lv4:Thunder Wave Lv9:Leer Lv12:Howl Lv17:Quick Attack Lv20:Spark Lv25:Odor Sleuth Lv28:Bite Lv33:Thunder Fang Lv36:Roar Lv41:Charge Lv49:ThunderEvolves into Manectric at Lv26
Shinx can learn Tackle, Leer (Level 5), Charge (Level 9), Bite (Level 13), Spark (Level 17), Roar (Level 21), Swagger (Level 25), Crunch (Level 29), Thunder Fang (Level 33), Scary Face (Level 37), and Discharge. (Level 41) It can learn these TMs and HMs as well: Roar, Toxic, Hidden Power, Light Screen, Protect, Rain Dance, Frustration, Iron Tail, Thunderbolt, Thunder, Return, Double Team, Shock Wave, Facade, Secret Power, Rest, Attract, Thief, Charge Beam, Endure, Flash, Thunder Wave, Captivate, Sleep Talk, Natural Gift, Swagger, Substitute, and Strength.
Pikachu has Thundershock and growl when you first get it at a low level. Then it learns: Tail whip at level 5 Thunder wave at level 10 Quick Attack at level 13 Double Team at level 18 Slam at level 21 Thunderbolt at level 26 Feint at level 29 Agility at level 34 Discharge at level 37 Light Screen at level 42 Then Thunder at level 45 It can also learn alot of TM's aswell.