at level 34 35 or 36
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It learns Flamethrower at level 34.
It takes a long time. You can either teach it a TM move flamethrower, breed a charmander, charmeleon or charizard with another Pokemon from the same group as it which knows flamethrower, or level up charmander to lv 32.
Blaziken does NOT learn flamethrower. but torchiccan. at level 42 i think!
Blaziken can only learn Flamethrower by TM, as it cannot learn it by leveling up. However, as a Torchic, it can learn Flamethrower at some level around level 50.
it can't learn flamethrower by itself but you can give it the TM flamethrower, you get that from the game corner