Could be whatchamacallit, 15 letters.
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Wonderful is a nice word that starts with "w".
methionylglutaminylarginyltyrosylglutamylseryllleucylpheny
Kennethrobertofitzwaterayjameseepatriciacashiichelsayybrianaeasthamaiecaittlinapaigerboothean.
supercalifragilisticexpialidocious.
21-letter wordbuckminsterfullerenes