methionylglutaminylarginyltyrosylglutamylseryllleucylpheny
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One very long word that starts with m is: microcryptocrystalline (22 letters)
Kennethrobertofitzwaterayjameseepatriciacashiichelsayybrianaeasthamaiecaittlinapaigerboothean.
supercalifragilisticexpialidocious.
21-letter wordbuckminsterfullerenes
Could be whatchamacallit, 15 letters.