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There are 2 episodes, one is episode 454 "Battling the Enemy Within". In this episode Ash is possesed by the spirit of the King of Pokelantis.

However the second one is episode 23 "The Tower of Terror" which is when a Haunter pulls Ash and Pikachu's soul out and says "You are like us now" as translated from Ghost Ash and takes them on a ride, while on this ride, Ash scares Misty and Brock in the process and finds out Misty really "does" care about him.

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Q: What is the episode called when ash turns into a ghost?
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