Cross chop or Dynamic punch, Swagger, Body slam, and any other move you want.
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mankey evolves into a primeape on level 28
(Leftovers) -Sleep Powder -Substitute -Leech Seed -Giga Drain Excellent moveset,
This is an opinion based question, as the "best" move can depend on many factors like prior set-up or power. Cross Chop would be Primeape's strongest move to be learned by leveling up due to it's 100 power, but it's accuracy is only 80%.
i think the best moveset for nidoking are: earthquake,sludgebomb,surf and megahorn..those are the moves that i put on my nidoking in fire red.
Hyper Beam is the best move it does 150