the best pokemon in black and white is victini you can catch him if you go on mystery gift after you get the victini card you can pick him up from the mail man next to the door at any pokemon center
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In Chargestone Cave. B2F is the best to find it.
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I have a stoutland and its my favorite non legendary Pokemon but Reshiram and Zekrom both are the strongest Pokemon on black and white. This is the link to see the srongest and fastest ETC.
The best place is probably in victory road or the route before it because of the high level Pokemon and if your asking there is no v.s seeker in Pokemon black an white
Best non-legendary water pokemon would be Gyarados. Best legendary water pokemon is Kyogre.