There are a few. There's blue stained glass, Lapis, Blue Wool, Cyan Wool, blue hardened clay, and diamond.
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You can craft things with Lapis like: A Lapis Lazuli block, light blue dye, cyan dye, purple dye, magenta dye and blue wool. You can check out Minecraft Wiki for some help and tips.
The hardest block in Minecraft is bedrock. It is completely unbreakable unless on creative mode.
Minecraft is a block related game. The developers never intended for their to be circles in minecraft.
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To place a block in Minecraft, just right click. Hold down left click to break it.