Luxury balls are a type of Poke ball for the game Pokemon. They are hard to find, so are worth more than other types of balls.
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Give a Pokemon in Pokemon Emerald, Sapphire, or Ruby a luxury ball to hold and trade to Fire Red. You can get extra luxury balls by winning a master rank contest after your Pokemon already has the ribbon. There is also one luxury ball in the abandoned ship, but you need dive. As far as I know, you cant get the luxery bal without tradeing with the other games I listed, or trade with someone who already has luxury balls. -BubbaJ
In Pokémon HeartGold and SoulSilver, the PokéBalls that you can get are: Poké Balls, Heal Balls, Great Balls, Net Balls, Dusk Balls, Friend Balls, Level Balls, Moon Balls, Heavy Balls, Lure Balls, Fast Balls, Luxury Balls, Ultra Balls, Love Balls, Nest Balls, Premier Balls, Quick Balls, Repeat Balls, Safari Balls, Timer Balls and Master Balls.
Apparently the prize for winning a Contest is a Luxury Ball; however, my source states that you must have won this Contest at least once before to earn the prize.
Goldenrod City Department Store drawing 2nd Prize [sunday]
you go to the abandoned ship and you need a Pokemon that knows diveI can type in large bold print too!you can get extra luxury balls by winning a master rank contest after your Pokemon already has the ribbon.