This episode was called: A Scare in the Air.
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Episode 1 of Season 10 OR if your counting all of the episodes of Pokemon Episode 467
Season 1, Episode 61 "The Misty Mermaid".
The very first episode of season 1.
i think it does the one who also does for bakura in yugioh last season of first series of course
Season 1 Episode 29 "The Punchy Pokemon!" ash meets hitmonchan and his trainer and enters the competition