May's full name on the Pokemon TV show is "May" since she does not have a last name like Ash Ketchum, Ash's Mom, Professor Oak and Gary Oak do.
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Ashley Ketchum
Her full name is Cynthia Roran Kale
More than all the Pokemon info you'll want to know is at Seribii.net, my favorite website.
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You can watch full length Pokemon episode on Cartoonnetwork.com or Pokemon.com/us