a level 100 mew
ignore this moron, the real answer is that we never find out yet.
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Pokeball Peril.
Pikachu was in the Poke Ball that Ash had received from Professor Oak.
You are probably referring to episode 67, from season 1. "Showdown at the Poke'-Corral." The opening is a dream sequence in which Ash gets suctioned into a pokeball. It turns out Mr. Mime is vacuuming Ash's face.
In DP051, Paul released his Chimchar because he thinks it's not strong enough (as usual) and in DP052, Ash officially catches it when he asked Chimchar once again to be on his team, and Chimchar agrees, so he throws a Pokeball in the air, and Chimchae jumps in. :D
In rocks inside the caves. Its random no cheats for that shittt.