They both have their perks, but if you're looking for consistency, or want to attach an item, its aerial ace, as it has 60 base power but Never Misses. If you don't care as much about either of those, acrobatics, which does 55 base damage with an item, but a whopping 110 without. It's pick your poison, but in game I would go with no item-acrobatics over aerial ace
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You can get Aerial Ace by buying it at the Battle Frontier.
You get aerial ace when you defeat Winona the gym leader in Fortree city.
No, Aerial Ace is not a purchasable TM in Pokemon Emerald. You can obtain it by defeating Winona.
Aerial Ace is found midway Route 213, near the coast, under a rock. Aerial Ace is found midway Route 213, near the coast, under a rock.
TM40- Aerial Ace can be found in Mt Mortar. You can also buy this TM at the Battle Frontier for 40BP.