Prize cards are the way the game is 'scored' and usually determines the winner of the game.
After both players draw their opening hand, they place the top six cards of their deck face down. These are their prize cards. Every time an opponent's pokemon is knocked out (by the direct result of an attack, but also due to poison/burn damage or self-inflicted KO such as the Take Down or Explosion moves) you place one Prize Card in your hand. Once a player takes his last Prize Card, that player wins the game. (The game is also won if the opponent runs out of pokemon and is unable to move one from the bench to the active zone once one is knocked out.)
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If one of your Pokemon faints for any reason (knocks itself out with its own attack, fainted from poison or burn) then the opponent gets a prize card.
Master Ball
It could be one of two things. - Certain Pokemon card game tournaments have exclusive cards that are given to winners. "Victory Medal" is one - it is a card unavailable in any pack or set, it was only given to people who won at a certain level during a tournament. - In a regular Pokemon TCG game, before the game starts, you take the top six cards off the top of your deck, keeping them face-down. These are your 'prize cards', and every time an opponent's Pokemon is knocked out, you take one. When you take your last one, you win the game.
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4th prize (1 matching number) = Background for dressing your Pokemon 3rd prize (2 " " ) = PP Up 2nd prize (3 " " ) = Exp. Share 1st prize (4 " " ) = Max Revive Grand prize (match all numbers) = Master Ball