in the anime it appears to be koffing or carnivine
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They are not in Pokemon HeartGold
There is not evidence that James from Pokemon is gay. If someone were gay, the reason why would be that they were born that way.
In "Pokemon Shipwreck" James admitted he liked Jessie, but she seemed to have more important things to do then have a crush on James. In the manga, Jessie and James are married and Jessie is pregnant.
Sweet Baby James
they are both 17, according to the Pokemon wiki