Some five letter words that end with K are:
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Five letter words that end in K are:blackblockbreakbrookchalkcheckchinkchuckchunkclickclockcluckclunkcrankcreekcroakcrookdrankdrinkdrunkflackflankflaskfleckflickflockflunkfrankfreakfriskfrockGreekkayakkioskknackknockquackquarkquickquirkshackshanksharksheikshirkshockshookshuckskulkskunkslacksleekslickslunksmacksmirksmocksnacksneakspanksparkspeakspeckspookspunkstackstalkstunkstarksteakstickstinkstockstorkstuckswank
Some five letter words ending in k include:slackstackstinkstunktrucktrunk
Some words that start and end with the letter K are:kayakkickkinfolkkinkkioskknackknapsackknock
Skunk
There are plenty of words that end with "tion", but none that start with K unfortunately!