Ash and friends meet Meloetta in Best Wishes episode 82 and continue to interact with it until episode 97. Meloetta also appears in the special episode Meloetta's Sparkling Recital, which was a short to air alongside the 15th Pokemon movie, Kyuurem Vs The Sword of Justice.
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the second episode.
Episode 1 of Season 10 OR if your counting all of the episodes of Pokemon Episode 467
No, Ash will not catch Meloetta.
In the Pokemon episode " Barry's Busting Out All Over!" Hope this helped!
well actually he never leaves if you saw the episode ash meets brock he says he needs someone to go with and ash volunteers so he stays with him forever