Ash had a double battle against Suwama in the Best Wishes episode number 077, 'Evolution by fire!'.
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It is in the 132nd episode of Pokemon DP vs paul the episode is called ash vs paul full battle part 2 it evolves when fighting against ursaring but then lose
Ash and friends meet Meloetta in Best Wishes episode 82 and continue to interact with it until episode 97. Meloetta also appears in the special episode Meloetta's Sparkling Recital, which was a short to air alongside the 15th Pokemon movie, Kyuurem Vs The Sword of Justice.
Pokemon yeah right naruto can kick ash's butt