Episode? if you mean level then 36
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Ash's monferno evolved into infernape in pokemon season 13(pokemon:dp:sinnoh league victors) episode no:6.
Ash's Chimchar evolves into a Monferno in Pokémon DP Galactic Battles episode 27. It is titled "Evolving Strategies". its ep 601
Inferno will evolve in Infernape starting in level 16. Infernape will evolve in Monferno starting in level 36.
Monferno evolves at Level 36, into Infernape.