ash's chimchar will evolve in a battle against Paul and chimchar will eventually collapse and faint against Paul's electabuzz
it evolve in " evolvin strategies" and the number of the episode is 595
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Ash's Chimchar evolves into a Monferno in Pokémon DP Galactic Battles episode 27. It is titled "Evolving Strategies". its ep 601
Following Paul releasing Chimchar in episode 50 glory blaze and Ash offers it to join his team in episode 51 smells like team spirit and Delighted, Chimchar joins Ash.
Yes, in episode 600 when Ash battles against Paul the 2nd part of their battle will be aired on youtube on June 18th (only in Japanese)
Ash receives Chimchar in the episode titled "Gettin' Twiggy With It!" which is the 52nd episode of the Diamond and Pearl series (Season 10). Chimchar was abandoned by its original Trainer, Paul, and Ash decides to take it under his wing. Chimchar eventually evolves into Monferno and then into Infernape, becoming one of Ash's most powerful and loyal Pokémon.
It is in the 132nd episode of Pokemon DP vs paul the episode is called ash vs paul full battle part 2 it evolves when fighting against ursaring but then lose