It makes enemies almost immune to melee hits (except grunts)
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the primary ones are: iron skull, black eye skull, tough luck skull, catch skull, cloud skull, famine skull, thunderstorm skull, tilt skull, mythic skull and the secondary ones are: blind skull, cowbell skull, gruntbirthday party skull, iwhbyd skull and all of them are accessible from the start so you dont have to look for them. hope i helped :P
you can find them in lake arrius caverns
The Third Mine. You can only find Mythic Stone after you get all the Cursed Tools and have all of those turned into Blessed Tools.
Mythic is the best.
it is very complicated to get the skull, you have to watch videos on how to get the skull