same as any other game
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there is no master ball in diamond and also great ball. but there is silver ball-silver ball is like a master ball.
You should use it on one of the 'roaming' pokemon, like Cresselia in Diamond/Pearl/Platinum.
You don't need to do anything. Just enter the code. When you throw any kind of Poke Ball, it will be like a Master Ball, even if the Pokemon is at full health.
capture legendary Pokemon like rayquaza.
no, you don't have to use your master ball on it. you could use it for any legendary Pokemon like mewtwo, or... you know what i mean!