a drink from the vending machine on the 5th floor of the dept store in veilstone city (it's to the upper left of the city from the pokecenter)
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you cannot give them a water you just cant....
The hiker (in Pokemon Diamond, Pearl and Platinum) to find a Happiny will be on Route 210, South Pokemon with Breeder Kahlil.
After you give the Old Charm to the lady in Celestic Town you get Surf
In Pokemon Diamond, Professor Rowan's assistant will give the play an Exp Share item on Route 206. One may also be won in the Pokemon Lottery on Jubilife TV.
Route 118, a fisherman will give it to you. Route 118.