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Assuming you mean after Koga (as Sabrina can be taken on about the same time). Head to Saffron, if you've not given the guards the tea from Celadon (in the mansion) do that first that will open the gates for you to get into Saffron, you will find Saffron overtaken by Team Rocket, head to Silph Co.

If you've beaten Sabrina as the 5th. Head South from Celadon via the Cycle Road or alternatively head South from Vermillion via Routes 12-15. (or straight south from Lavender). They will both lead you to Fuchsia and require you to have gotten the Pokeflute from the Lavender Tower as both have Snorlax in the way.

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Q: What do you do after you defeat the 5th gym leader in Pokemon LeafGreen?
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